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Disinfection Byproducts

Chloroform

Chloroform is the most common trihalomethane and the surrogate the NSF/ANSI 53 VOC test uses for the family. It is regulated as part of total trihalomethanes (TTHM limit 80 ppb). Its EPA health goal (MCLG) is 0.07 mg/L.

EPA MCLG

0.07 mg/L

The level in drinking water below which there is no known or expected risk to health. This is a goal, not an enforceable limit.

Health Effects

Long-term exposure is associated with an increased risk of bladder cancer at the population level; the EPA and IARC classify it as a possible or probable human carcinogen. Liver, kidney, and central-nervous-system effects have been observed at high doses. The risk is chronic and lifetime, not acute.

Common Sources

  • Byproduct of disinfecting drinking water with chlorine
  • Formed when chlorine reacts with natural organic matter such as decaying leaves, runoff, and algae
  • Levels are highest in warm-season surface water

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How to Remove Chloroform

How do I get rid of Chloroform in drinking water?

For Chloroform, the verified treatment is activated carbon. Activated carbon is a conditional treatment. Requires an NSF/ANSI 53 TTHM-certified carbon and adequate contact time; carbon adsorbs TTHM but breaks through over time. EPA's municipal BAT is GAC10/GAC20 with enhanced coagulation or softening.

Source: NSF/ANSI 53 (TTHM reduction) / EPA Stage 1 & 2 D/DBP Rule, 40 CFR 141.64

What filter certification covers Chloroform?

Activated carbon is certified under NSF/ANSI 53. Check that the certification listing names Chloroform or its group: a certification to a standard is not a certification for every contaminant in it.

Source: NSF/ANSI 53 (TTHM reduction) / EPA Stage 1 & 2 D/DBP Rule, 40 CFR 141.64

Does a basic water filter pitcher remove Chloroform?

Only if it is certified for it. A basic pitcher is an activated-carbon device and carbon does adsorb Chloroform, but only a pitcher certified under NSF/ANSI 53 for this reduction has been tested to do it, and the cartridge breaks through as it loads โ€” so replacement on schedule is part of the answer. An NSF/ANSI 42 certification, which most pitchers carry, covers taste and odor only and says nothing about Chloroform.

Source: NSF/ANSI 53 (TTHM reduction) / EPA Stage 1 & 2 D/DBP Rule, 40 CFR 141.64

Does boiling water remove Chloroform?

Mostly, from the water you drink โ€” and this is the half of the disinfection-byproduct group where that is true. Trihalomethanes are volatile, so heating drives Chloroform out of the water rather than destroying it: EPA measured volatilization losses approaching 75% when water was boiled even for brief periods, and 90% when the boiled water was poured and served. It leaves as vapour into the room, which is why the cited EPA work is about ingestion exposure โ€” it lowers what you swallow, not what the household breathes. Open containers lost more than closed ones, because a lid traps the vapour. None of this is advice to boil your water: boiling does nothing for the non-volatile half of this group and can raise haloacetic acids where residual chlorine is present, so it is no treatment for disinfection byproducts as a group.

Source: EPA Science Inventory (2000), "Reduction of Ingestion Exposure to Trihalomethanes Due to Volatilization"; Ma X. et al., Science of the Total Environment 2024;906:167657

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Is Chloroform in your water?

Chloroform has been recorded above its health guideline in 14 cities, serving 0.0M people. Each system below was judged against a goal of 70 PPB.

Most affected systems, by population served

and 4 more cities with a recorded result above the guideline

These are the largest systems that reported a result above the guideline โ€” not the highest results. A city missing from this list has not been shown to be clean: it may have no Chloroform result on file at all. We publish a level only where a system reported one.

Check your city or ZIP code for Chloroform

Part of a group: disinfection byproducts

This contaminant is rarely measured on its own. Disinfection byproducts in drinking water covers the whole group โ€” what they are, which limits are enforceable, and where they come from.

Others in this group

About the EPA MCLG

The EPA MCLG is the level of a contaminant in drinking water below which there is no known or expected risk to health. It is a non-enforceable public health goal, and is often stricter than the legal limit (MCL) water systems must meet.

Contaminant Type

Chloroform is classified as a Disinfection Byproducts contaminant.

Check Your Water

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